File 1 : Z:\instruments-archive\XRD-current\Austin\MCTeCO\ML_Westley_20240202_2_AMF-CTO_T2_dried+Si_std_2hr_last_check.raw Range Number : 1 R-Values Rexp : 1.20 Rwp : 1.66 Rp : 1.28 GOF : 1.38 Rexp`: 10.84 Rwp`: 15.00 Rp` : 23.26 DW : 1.18 Quantitative Analysis - Rietveld Phase 1 : Structure 73.6(4) % Phase 2 : Structure 26.4(4) % Background Chebychev polynomial, Coefficient 0 6636(3) 1 -3649(5) 2 343(5) 3 579(5) 4 13(5) 5 -578(4) 6 478(4) 7 -92(4) 8 -143(4) 9 63(4) 10 10(4) Instrument Primary radius (mm) 200.5 Secondary radius (mm) 200.5 Linear PSD 2Th angular range (°) 3 FDS angle (°) 0.6 Corrections Specimen displacement 0.118(5) LP Factor 0 Miscellaneous Convolution Steps 3 Start X 12 Finish X 60 Structure 1 Phase name Structure R-Bragg 0.363 Spacegroup C2/c Scale 0.0000608(4) Cell Mass 2412(6) Cell Volume (Å^3) 758.20(3) Wt% - Rietveld 73.6(4) Double-Voigt|Approach Cry size Lorentzian 151(4) k: 1 LVol-IB (nm) 96(4) k: 0.89 LVol-FWHM (nm) 135(4) Crystal Linear Absorption Coeff. (1/cm) 1178.39(15) Crystal Density (g/cm^3) 5.283(13) Preferred Orientation Spherical Harmonics Order 6 y00 1 y20 0.123(15) y22m 0.033(12) y22p 0.009(14) y40 0.096(18) y42m -0.011(11) y42p -0.083(13) y44m -0.054(12) y44p 0.04(2) y60 0.04(2) y62m 0.106(13) y62p -0.051(13) y64m -0.076(13) y64p 0.161(15) y66m 0.077(18) y66p -0.036(17) Lattice parameters a (Å) 12.6792(3) b (Å) 5.20810(13) c (Å) 11.6251(3) beta (°) 99.003(2) Site Np x y z Atom Occ Beq Co1 8 0.2731(7) 0.311(2) 0.1484(8) Co 0.930(11) 1.6(4) Te1 4 0.50000 0.6613(11) 0.25000 Te 0.962(7) 1.8(3) Te2 8 0.3632(3) 0.3086(7) 0.4440(4) Te 0.959(5) 1.9(2) O1 8 0.422(3) 0.463(7) 0.160(3) O 1.00(4) 0.2(13) O2 8 0.376(2) 0.609(6) 0.384(3) O 1.00(4) 0.2(12) O3 8 0.300(3) 0.139(8) 0.314(3) O 0.95(4) 1.9(12) O4 8 0.273(3) 0.482(6) 0.481(3) O 0.98(5) 1.1(16) Structure 2 Phase name Structure R-Bragg 0.483 Spacegroup Fd-3m Scale 0.00111(2) Cell Mass 224.684 Cell Volume (Å^3) 160.14989 Wt% - Rietveld 26.4(4) Double-Voigt|Approach Cry size Lorentzian 470(30) k: 1 LVol-IB (nm) 299(18) k: 0.89 LVol-FWHM (nm) 420(30) Crystal Linear Absorption Coeff. (1/cm) 148.024 Crystal Density (g/cm^3) 2.330 Preferred Orientation Spherical Harmonics Order 4 k00 1 k41 -0.32(4) Lattice parameters a (Å) 5.4305300 Site Np x y z Atom Occ Beq Si1 8 0.00000 0.00000 0.00000 Si 1 3.1(8)